Synthesis and Structure of Platinum Complexes with Organyltriphenylphosphonium Chlorides and DMSO
- Авторлар: Sharutin V.1, Sharutina O.1, Senchurin V.1, Tkacheva A.1
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Мекемелер:
- State Educational Institution South Ural Research University
- Шығарылым: Том 88, № 7 (2018)
- Беттер: 1456-1461
- Бөлім: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/222322
- DOI: https://doi.org/10.1134/S1070363218070174
- ID: 222322
Дәйексөз келтіру
Аннотация
Complexes [Ph3PCH2C(O)Me][PtCl3(DMSO-S)] and [Ph3PCH2CH=CH2][PtCl3(DMSO-S)] were synthesized by the reaction of organyltriphenylphosphonium chloride with potassium tetrachloroplatinate (2 : 1) in dimethyl sulfoxide. The reaction of but-2-enylbis(triphenylphosphonim) dichloride with potassium hexachloroplatinate or hexachloroplatinic acid leads to the formation of the complex [Ph3PCH2CH=CHCH2PPh3][PtCl5(DMSO-S)]2. Phosphorus atoms in the cations of the synthesized complexes have a tetrahedral surrounding, and the anions [PtCl5(DMSO-S)]− are square in shape.
Авторлар туралы
V. Sharutin
State Educational Institution South Ural Research University
Хат алмасуға жауапты Автор.
Email: vvsharutin@rambler.ru
Ресей, pr. Lenina 76, Chelyabinsk, 454080
O. Sharutina
State Educational Institution South Ural Research University
Email: vvsharutin@rambler.ru
Ресей, pr. Lenina 76, Chelyabinsk, 454080
V. Senchurin
State Educational Institution South Ural Research University
Email: vvsharutin@rambler.ru
Ресей, pr. Lenina 76, Chelyabinsk, 454080
A. Tkacheva
State Educational Institution South Ural Research University
Email: vvsharutin@rambler.ru
Ресей, pr. Lenina 76, Chelyabinsk, 454080