Synthesis and Structure of Platinum Complexes with Organyltriphenylphosphonium Chlorides and DMSO
- 作者: Sharutin V.1, Sharutina O.1, Senchurin V.1, Tkacheva A.1
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隶属关系:
- State Educational Institution South Ural Research University
- 期: 卷 88, 编号 7 (2018)
- 页面: 1456-1461
- 栏目: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/222322
- DOI: https://doi.org/10.1134/S1070363218070174
- ID: 222322
如何引用文章
详细
Complexes [Ph3PCH2C(O)Me][PtCl3(DMSO-S)] and [Ph3PCH2CH=CH2][PtCl3(DMSO-S)] were synthesized by the reaction of organyltriphenylphosphonium chloride with potassium tetrachloroplatinate (2 : 1) in dimethyl sulfoxide. The reaction of but-2-enylbis(triphenylphosphonim) dichloride with potassium hexachloroplatinate or hexachloroplatinic acid leads to the formation of the complex [Ph3PCH2CH=CHCH2PPh3][PtCl5(DMSO-S)]2. Phosphorus atoms in the cations of the synthesized complexes have a tetrahedral surrounding, and the anions [PtCl5(DMSO-S)]− are square in shape.
作者简介
V. Sharutin
State Educational Institution South Ural Research University
编辑信件的主要联系方式.
Email: vvsharutin@rambler.ru
俄罗斯联邦, pr. Lenina 76, Chelyabinsk, 454080
O. Sharutina
State Educational Institution South Ural Research University
Email: vvsharutin@rambler.ru
俄罗斯联邦, pr. Lenina 76, Chelyabinsk, 454080
V. Senchurin
State Educational Institution South Ural Research University
Email: vvsharutin@rambler.ru
俄罗斯联邦, pr. Lenina 76, Chelyabinsk, 454080
A. Tkacheva
State Educational Institution South Ural Research University
Email: vvsharutin@rambler.ru
俄罗斯联邦, pr. Lenina 76, Chelyabinsk, 454080
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