New Tridentate Schiff Base, Product of Condensation of 4-Methyl-7-hydroxy-8-formylcoumarin and N-Aminomercaptotriazole: Synthesis, Structure, and Complex Formation
- Авторлар: Popov L.1, Borodkin S.1, Vasil’chenko I.2, Vlasenko V.3, Borodkin G.2, Zubavichus Y.4, Levchenkov S.1,5, Tupolova Y.1, Revinskii Y.5, Shcherbakov I.1
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Мекемелер:
- Southern Federal University
- Rostov-on-Don, Research Institute of Physical and Organic Chemistry
- Rostov-on-Don, Research Institute of Physics
- National Research Center “Kurchatov Institute,”
- Southern Scientific Center of the Russian Academy of Sciences
- Шығарылым: Том 88, № 7 (2018)
- Беттер: 1441-1450
- Бөлім: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/222319
- DOI: https://doi.org/10.1134/S1070363218070150
- ID: 222319
Дәйексөз келтіру
Аннотация
A new Schiff base was prepared by the reaction of 4-methyl-7-hydroxy-8-formylcoumarin with N-aminomercaptotriazole. In solution and in solid phase the compound was shown to exist in the thione form. The compound reacts with Cu(II), Ni(II), Zn(II) and Cd(II) ions depending on the metal salt to give complexes of composition ML2 or MHLX, where HL is monodeprotonated form of the ligand. Cu(II) and Ni(II) complexes were studied by spectral and magnetochemical methods. The Zn(II) and Cd(II) complexes exhibit fluorescence.
Негізгі сөздер
Авторлар туралы
L. Popov
Southern Federal University
Хат алмасуға жауапты Автор.
Email: ldpopov@mail.ru
Ресей, ul. Zorge 7, Rostov-on-Don, 344090
S. Borodkin
Southern Federal University
Email: ldpopov@mail.ru
Ресей, ul. Zorge 7, Rostov-on-Don, 344090
I. Vasil’chenko
Rostov-on-Don, Research Institute of Physical and Organic Chemistry
Email: ldpopov@mail.ru
Ресей, Rostov-on-Don
V. Vlasenko
Rostov-on-Don, Research Institute of Physics
Email: ldpopov@mail.ru
Ресей, Rostov-on-Don
G. Borodkin
Rostov-on-Don, Research Institute of Physical and Organic Chemistry
Email: ldpopov@mail.ru
Ресей, Rostov-on-Don
Ya. Zubavichus
National Research Center “Kurchatov Institute,”
Email: ldpopov@mail.ru
Ресей, Moscow
S. Levchenkov
Southern Federal University; Southern Scientific Center of the Russian Academy of Sciences
Email: ldpopov@mail.ru
Ресей, ul. Zorge 7, Rostov-on-Don, 344090; Rostov-on-Don
Yu. Tupolova
Southern Federal University
Email: ldpopov@mail.ru
Ресей, ul. Zorge 7, Rostov-on-Don, 344090
Yu. Revinskii
Southern Scientific Center of the Russian Academy of Sciences
Email: ldpopov@mail.ru
Ресей, Rostov-on-Don
I. Shcherbakov
Southern Federal University
Email: ldpopov@mail.ru
Ресей, ul. Zorge 7, Rostov-on-Don, 344090
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