New Tridentate Schiff Base, Product of Condensation of 4-Methyl-7-hydroxy-8-formylcoumarin and N-Aminomercaptotriazole: Synthesis, Structure, and Complex Formation
- 作者: Popov L.1, Borodkin S.1, Vasil’chenko I.2, Vlasenko V.3, Borodkin G.2, Zubavichus Y.4, Levchenkov S.1,5, Tupolova Y.1, Revinskii Y.5, Shcherbakov I.1
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隶属关系:
- Southern Federal University
- Rostov-on-Don, Research Institute of Physical and Organic Chemistry
- Rostov-on-Don, Research Institute of Physics
- National Research Center “Kurchatov Institute,”
- Southern Scientific Center of the Russian Academy of Sciences
- 期: 卷 88, 编号 7 (2018)
- 页面: 1441-1450
- 栏目: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/222319
- DOI: https://doi.org/10.1134/S1070363218070150
- ID: 222319
如何引用文章
详细
A new Schiff base was prepared by the reaction of 4-methyl-7-hydroxy-8-formylcoumarin with N-aminomercaptotriazole. In solution and in solid phase the compound was shown to exist in the thione form. The compound reacts with Cu(II), Ni(II), Zn(II) and Cd(II) ions depending on the metal salt to give complexes of composition ML2 or MHLX, where HL is monodeprotonated form of the ligand. Cu(II) and Ni(II) complexes were studied by spectral and magnetochemical methods. The Zn(II) and Cd(II) complexes exhibit fluorescence.
作者简介
L. Popov
Southern Federal University
编辑信件的主要联系方式.
Email: ldpopov@mail.ru
俄罗斯联邦, ul. Zorge 7, Rostov-on-Don, 344090
S. Borodkin
Southern Federal University
Email: ldpopov@mail.ru
俄罗斯联邦, ul. Zorge 7, Rostov-on-Don, 344090
I. Vasil’chenko
Rostov-on-Don, Research Institute of Physical and Organic Chemistry
Email: ldpopov@mail.ru
俄罗斯联邦, Rostov-on-Don
V. Vlasenko
Rostov-on-Don, Research Institute of Physics
Email: ldpopov@mail.ru
俄罗斯联邦, Rostov-on-Don
G. Borodkin
Rostov-on-Don, Research Institute of Physical and Organic Chemistry
Email: ldpopov@mail.ru
俄罗斯联邦, Rostov-on-Don
Ya. Zubavichus
National Research Center “Kurchatov Institute,”
Email: ldpopov@mail.ru
俄罗斯联邦, Moscow
S. Levchenkov
Southern Federal University; Southern Scientific Center of the Russian Academy of Sciences
Email: ldpopov@mail.ru
俄罗斯联邦, ul. Zorge 7, Rostov-on-Don, 344090; Rostov-on-Don
Yu. Tupolova
Southern Federal University
Email: ldpopov@mail.ru
俄罗斯联邦, ul. Zorge 7, Rostov-on-Don, 344090
Yu. Revinskii
Southern Scientific Center of the Russian Academy of Sciences
Email: ldpopov@mail.ru
俄罗斯联邦, Rostov-on-Don
I. Shcherbakov
Southern Federal University
Email: ldpopov@mail.ru
俄罗斯联邦, ul. Zorge 7, Rostov-on-Don, 344090
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