Polarizability constant of iodine as substituent in correlation analysis
- Авторлар: Kurskii Y.1, Khamaletdinova N.1, Egorochkin A.1
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Мекемелер:
- Razuvaev Institute of Organometallic Chemistry
- Шығарылым: Том 87, № 8 (2017)
- Беттер: 1651-1655
- Бөлім: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/220929
- DOI: https://doi.org/10.1134/S1070363217080011
- ID: 220929
Дәйексөз келтіру
Аннотация
Correlation equations describing the influence of inductive, resonance, polarizability, and steric effects of the substituents on the parameters of IR, NQR, NMR, and Mössbauer spectra as well as ionization and activation energies have been considered for 13 reaction (indicator) series. Using the obtained equations, we have calculated the earlier unknown polarizability constant of iodine substituent (σα =–0.71). The relation between the σα constant of substituent X and polarization of atoms of X has been found for the CH3X (H, F, Cl, Br, I) series.
Авторлар туралы
Yu. Kurskii
Razuvaev Institute of Organometallic Chemistry
Хат алмасуға жауапты Автор.
Email: kursk@iomc.ras.ru
Ресей, ul. Tropinina 49, Nizhny Novgorod, 603950
N. Khamaletdinova
Razuvaev Institute of Organometallic Chemistry
Email: kursk@iomc.ras.ru
Ресей, ul. Tropinina 49, Nizhny Novgorod, 603950
A. Egorochkin
Razuvaev Institute of Organometallic Chemistry
Email: kursk@iomc.ras.ru
Ресей, ul. Tropinina 49, Nizhny Novgorod, 603950