Polarizability constant of iodine as substituent in correlation analysis
- 作者: Kurskii Y.1, Khamaletdinova N.1, Egorochkin A.1
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隶属关系:
- Razuvaev Institute of Organometallic Chemistry
- 期: 卷 87, 编号 8 (2017)
- 页面: 1651-1655
- 栏目: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/220929
- DOI: https://doi.org/10.1134/S1070363217080011
- ID: 220929
如何引用文章
详细
Correlation equations describing the influence of inductive, resonance, polarizability, and steric effects of the substituents on the parameters of IR, NQR, NMR, and Mössbauer spectra as well as ionization and activation energies have been considered for 13 reaction (indicator) series. Using the obtained equations, we have calculated the earlier unknown polarizability constant of iodine substituent (σα =–0.71). The relation between the σα constant of substituent X and polarization of atoms of X has been found for the CH3X (H, F, Cl, Br, I) series.
作者简介
Yu. Kurskii
Razuvaev Institute of Organometallic Chemistry
编辑信件的主要联系方式.
Email: kursk@iomc.ras.ru
俄罗斯联邦, ul. Tropinina 49, Nizhny Novgorod, 603950
N. Khamaletdinova
Razuvaev Institute of Organometallic Chemistry
Email: kursk@iomc.ras.ru
俄罗斯联邦, ul. Tropinina 49, Nizhny Novgorod, 603950
A. Egorochkin
Razuvaev Institute of Organometallic Chemistry
Email: kursk@iomc.ras.ru
俄罗斯联邦, ul. Tropinina 49, Nizhny Novgorod, 603950
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