Generation of the atrane cations by nuclear-chemical method: Quantum-chemical study
- Авторлар: Ignat’ev I.1, Kochina T.2, Avrorin V.1, Ermolenko Y.1
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Мекемелер:
- St. Petersburg State University
- Grebenshchikov Institute of Silicate Chemistry
- Шығарылым: Том 87, № 6 (2017)
- Беттер: 1119-1124
- Бөлім: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/220121
- DOI: https://doi.org/10.1134/S1070363217060032
- ID: 220121
Дәйексөз келтіру
Аннотация
Comparative analysis of equilibrium structures of cations [RM(OCH2CH2)2NCH3]+ (M = Si, Ge; R = F, Me, Ph) and the corresponding neutral compounds HRM(OCH2CH2)2NCH3 was performed based on quantum-chemical calculations. The possibility was analyzed for expanding nuclear-chemical method to generation of cations having the atrane structure. Quantum-chemical method was applied to estimate the heights of barriers to hydrolysis by the М–О bond in ocanes acting as the sources of the corresponding cations with the atrane structure.
Негізгі сөздер
Авторлар туралы
I. Ignat’ev
St. Petersburg State University
Email: t-kochina@mail.ru
Ресей, St. Petersburg
T. Kochina
Grebenshchikov Institute of Silicate Chemistry
Хат алмасуға жауапты Автор.
Email: t-kochina@mail.ru
Ресей, nab. Makarova 2, St. Petersburg, 199034
V. Avrorin
St. Petersburg State University
Email: t-kochina@mail.ru
Ресей, St. Petersburg
Yu. Ermolenko
St. Petersburg State University
Email: t-kochina@mail.ru
Ресей, St. Petersburg