Generation of the atrane cations by nuclear-chemical method: Quantum-chemical study
- 作者: Ignat’ev I.1, Kochina T.2, Avrorin V.1, Ermolenko Y.1
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隶属关系:
- St. Petersburg State University
- Grebenshchikov Institute of Silicate Chemistry
- 期: 卷 87, 编号 6 (2017)
- 页面: 1119-1124
- 栏目: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/220121
- DOI: https://doi.org/10.1134/S1070363217060032
- ID: 220121
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详细
Comparative analysis of equilibrium structures of cations [RM(OCH2CH2)2NCH3]+ (M = Si, Ge; R = F, Me, Ph) and the corresponding neutral compounds HRM(OCH2CH2)2NCH3 was performed based on quantum-chemical calculations. The possibility was analyzed for expanding nuclear-chemical method to generation of cations having the atrane structure. Quantum-chemical method was applied to estimate the heights of barriers to hydrolysis by the М–О bond in ocanes acting as the sources of the corresponding cations with the atrane structure.
作者简介
I. Ignat’ev
St. Petersburg State University
Email: t-kochina@mail.ru
俄罗斯联邦, St. Petersburg
T. Kochina
Grebenshchikov Institute of Silicate Chemistry
编辑信件的主要联系方式.
Email: t-kochina@mail.ru
俄罗斯联邦, nab. Makarova 2, St. Petersburg, 199034
V. Avrorin
St. Petersburg State University
Email: t-kochina@mail.ru
俄罗斯联邦, St. Petersburg
Yu. Ermolenko
St. Petersburg State University
Email: t-kochina@mail.ru
俄罗斯联邦, St. Petersburg