Synthesis and structure of silver complexes [Ph3(i-Pr)P]+2[Ag2I4]2− and [Ph3MeP]+n[Ag3I4]–n
- Авторлар: Sharutin V.1, Sharutina O.1, Senchurin V.1, Neudachina A.1
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Мекемелер:
- National Southern Ural State Research University
- Шығарылым: Том 86, № 7 (2016)
- Беттер: 1653-1658
- Бөлім: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/215703
- DOI: https://doi.org/10.1134/S1070363216070203
- ID: 215703
Дәйексөз келтіру
Аннотация
Complexes [Ph3(i-Pr)P]+2[Ag2I4]2- and [Ph3MeP]+n[Ag3I4]–n were synthesized by the reaction of alkyl (triphenyl)phosphonium iodides with silver iodide in dimethyl sulfoxide. Triphenylalkylphosphonium cations have a tetrahedral configuration. Silver atoms in binuclear anions [Ag2I4]2- are characterized by trigonal coordination, the iodine coordination number being 2 or 1. In the polymeric anions [Ag3I4]–n the silver coordination number is 4 and that of iodine, 2, 3, or 4.
Авторлар туралы
V. Sharutin
National Southern Ural State Research University
Хат алмасуға жауапты Автор.
Email: vvsharutin@rambler.ru
Ресей, pr. Lenina 76, Chelyabinsk, 454080
O. Sharutina
National Southern Ural State Research University
Email: vvsharutin@rambler.ru
Ресей, pr. Lenina 76, Chelyabinsk, 454080
V. Senchurin
National Southern Ural State Research University
Email: vvsharutin@rambler.ru
Ресей, pr. Lenina 76, Chelyabinsk, 454080
A. Neudachina
National Southern Ural State Research University
Email: vvsharutin@rambler.ru
Ресей, pr. Lenina 76, Chelyabinsk, 454080