Email this article Synthesis and structure of silver complexes [Ph3(i-Pr)P]+2[Ag2I4]2− and [Ph3MeP]+n[Ag3I4]–n
- Authors: Sharutin V.V.1, Sharutina O.K.1, Senchurin V.S.1, Neudachina A.N.1
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Affiliations:
- National Southern Ural State Research University
- Issue: Vol 86, No 7 (2016)
- Pages: 1653-1658
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/215703
- DOI: https://doi.org/10.1134/S1070363216070203
- ID: 215703
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Abstract
Complexes [Ph3(i-Pr)P]+2[Ag2I4]2- and [Ph3MeP]+n[Ag3I4]–n were synthesized by the reaction of alkyl (triphenyl)phosphonium iodides with silver iodide in dimethyl sulfoxide. Triphenylalkylphosphonium cations have a tetrahedral configuration. Silver atoms in binuclear anions [Ag2I4]2- are characterized by trigonal coordination, the iodine coordination number being 2 or 1. In the polymeric anions [Ag3I4]–n the silver coordination number is 4 and that of iodine, 2, 3, or 4.
About the authors
V. V. Sharutin
National Southern Ural State Research University
Author for correspondence.
Email: vvsharutin@rambler.ru
Russian Federation, pr. Lenina 76, Chelyabinsk, 454080
O. K. Sharutina
National Southern Ural State Research University
Email: vvsharutin@rambler.ru
Russian Federation, pr. Lenina 76, Chelyabinsk, 454080
V. S. Senchurin
National Southern Ural State Research University
Email: vvsharutin@rambler.ru
Russian Federation, pr. Lenina 76, Chelyabinsk, 454080
A. N. Neudachina
National Southern Ural State Research University
Email: vvsharutin@rambler.ru
Russian Federation, pr. Lenina 76, Chelyabinsk, 454080
