Synthesis, crystal structure, and magnetic characteristics of chiral cyanide-bridged Fe–Cu complex
- Авторлар: Xue C.1, Yuan H.2, Zhang H.1, Zhang D.1
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Мекемелер:
- College of Chemical Engineering
- Jiangxi Institute of Materia Medica
- Шығарылым: Том 86, № 4 (2016)
- Беттер: 953-957
- Бөлім: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/214814
- DOI: https://doi.org/10.1134/S1070363216040332
- ID: 214814
Дәйексөз келтіру
Аннотация
Based on the building blocks, trans-dicyanide Fe(III) precursor and chiral amine Cu(II) compound, the chiral cyanide-bridged heterometallic Fe(III)–Cu(II) complex with the formula {[Cu(R/R-Chxn)2Fe(bpmb)·(CN)2][Fe(bpmb)(CN)2]}·CH3OH·H2O (1) [bpmb2– = 1,2-bis(pyridine-2-carboxamido)-4-methylbenzenate, R,R-Chxn = R,R-1,2-diaminocyclohexane] has been synthesized and characterized by elemental analysis, IR spectra and X-ray analysis. The latter revealed that the complex contained the cyanide-bridged cationic binuclear entity and free anionic cyanide building block. The complex demonstrated weak ferromagnetic coupling between neighboring Fe(III) and Cu(II) ions via the bridging cyanide group.
Негізгі сөздер
Авторлар туралы
C. Xue
College of Chemical Engineering
Email: dpzhang73@126.com
ҚХР, Zibo, 255049
H. Yuan
Jiangxi Institute of Materia Medica
Email: dpzhang73@126.com
ҚХР, Nanchang, 330029
H. Zhang
College of Chemical Engineering
Email: dpzhang73@126.com
ҚХР, Zibo, 255049
D. Zhang
College of Chemical Engineering
Хат алмасуға жауапты Автор.
Email: dpzhang73@126.com
ҚХР, Zibo, 255049