Synthesis, crystal structure, and magnetic characteristics of chiral cyanide-bridged Fe–Cu complex
- 作者: Xue C.1, Yuan H.2, Zhang H.1, Zhang D.1
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隶属关系:
- College of Chemical Engineering
- Jiangxi Institute of Materia Medica
- 期: 卷 86, 编号 4 (2016)
- 页面: 953-957
- 栏目: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/214814
- DOI: https://doi.org/10.1134/S1070363216040332
- ID: 214814
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详细
Based on the building blocks, trans-dicyanide Fe(III) precursor and chiral amine Cu(II) compound, the chiral cyanide-bridged heterometallic Fe(III)–Cu(II) complex with the formula {[Cu(R/R-Chxn)2Fe(bpmb)·(CN)2][Fe(bpmb)(CN)2]}·CH3OH·H2O (1) [bpmb2– = 1,2-bis(pyridine-2-carboxamido)-4-methylbenzenate, R,R-Chxn = R,R-1,2-diaminocyclohexane] has been synthesized and characterized by elemental analysis, IR spectra and X-ray analysis. The latter revealed that the complex contained the cyanide-bridged cationic binuclear entity and free anionic cyanide building block. The complex demonstrated weak ferromagnetic coupling between neighboring Fe(III) and Cu(II) ions via the bridging cyanide group.
作者简介
C. Xue
College of Chemical Engineering
Email: dpzhang73@126.com
中国, Zibo, 255049
H. Yuan
Jiangxi Institute of Materia Medica
Email: dpzhang73@126.com
中国, Nanchang, 330029
H. Zhang
College of Chemical Engineering
Email: dpzhang73@126.com
中国, Zibo, 255049
D. Zhang
College of Chemical Engineering
编辑信件的主要联系方式.
Email: dpzhang73@126.com
中国, Zibo, 255049