Synthesis and structure of tetra- and triphenylantimony 2,4,6-trichlorophenoxides
- Авторлар: Sharutin V.1, Sharutina O.1, Senchurin V.1, Shchelokov A.1
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Мекемелер:
- National Research Southern Ural State University
- Шығарылым: Том 86, № 1 (2016)
- Беттер: 85-91
- Бөлім: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/213428
- DOI: https://doi.org/10.1134/S1070363216010151
- ID: 213428
Дәйексөз келтіру
Аннотация
The reaction of pentaphenylantimony with 2,4,6-trichlorophenol or bis(2,4,6-trichlorophenoxy)- triphenylantimony in toluene afforded (2,4,6-trichlorophenoxy)tetraphenylantimony. The reaction of triphenylantimony with tert-butyl hydroperoxide and 2,4,6-trichlorophenol led to the formation of bis(2,4,6-trichlorophenoxy) triphenylantimony; further reaction of the latter with triphenylantimony dichloride provided (2,4,6-trichlorophenoxy)triphenylantimony chloride. According to the XRD data, the antimony atoms in the prepared compounds had distorted trigonal-bipyramidal coordination with electronegative ligands in axial positions.
Авторлар туралы
V. Sharutin
National Research Southern Ural State University
Хат алмасуға жауапты Автор.
Email: vvsharutin@rambler.ru
Ресей, pr. Lenina 76, Chelyabinsk, 454080
O. Sharutina
National Research Southern Ural State University
Email: vvsharutin@rambler.ru
Ресей, pr. Lenina 76, Chelyabinsk, 454080
V. Senchurin
National Research Southern Ural State University
Email: vvsharutin@rambler.ru
Ресей, pr. Lenina 76, Chelyabinsk, 454080
A. Shchelokov
National Research Southern Ural State University
Email: vvsharutin@rambler.ru
Ресей, pr. Lenina 76, Chelyabinsk, 454080