Synthesis and structure of tetra- and triphenylantimony 2,4,6-trichlorophenoxides
- Authors: Sharutin V.V.1, Sharutina O.K.1, Senchurin V.S.1, Shchelokov A.O.1
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Affiliations:
- National Research Southern Ural State University
- Issue: Vol 86, No 1 (2016)
- Pages: 85-91
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/213428
- DOI: https://doi.org/10.1134/S1070363216010151
- ID: 213428
Cite item
Abstract
The reaction of pentaphenylantimony with 2,4,6-trichlorophenol or bis(2,4,6-trichlorophenoxy)- triphenylantimony in toluene afforded (2,4,6-trichlorophenoxy)tetraphenylantimony. The reaction of triphenylantimony with tert-butyl hydroperoxide and 2,4,6-trichlorophenol led to the formation of bis(2,4,6-trichlorophenoxy) triphenylantimony; further reaction of the latter with triphenylantimony dichloride provided (2,4,6-trichlorophenoxy)triphenylantimony chloride. According to the XRD data, the antimony atoms in the prepared compounds had distorted trigonal-bipyramidal coordination with electronegative ligands in axial positions.
About the authors
V. V. Sharutin
National Research Southern Ural State University
Author for correspondence.
Email: vvsharutin@rambler.ru
Russian Federation, pr. Lenina 76, Chelyabinsk, 454080
O. K. Sharutina
National Research Southern Ural State University
Email: vvsharutin@rambler.ru
Russian Federation, pr. Lenina 76, Chelyabinsk, 454080
V. S. Senchurin
National Research Southern Ural State University
Email: vvsharutin@rambler.ru
Russian Federation, pr. Lenina 76, Chelyabinsk, 454080
A. O. Shchelokov
National Research Southern Ural State University
Email: vvsharutin@rambler.ru
Russian Federation, pr. Lenina 76, Chelyabinsk, 454080
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