Email this article Reactions of silicon hydrides catalyzed by rhodium(III) sulfoxide complexes
- Authors: Eliseeva A.A.1, Prudnikova E.G.1, Panikorovskii T.L.2, Skvortsov N.K.1
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Affiliations:
- St. Petersburg State Institute of Technology (Technical University)
- St. Petersburg State University
- Issue: Vol 87, No 8 (2017)
- Pages: 1884-1886
- Section: Letters to the Editor
- URL: https://journals.rcsi.science/1070-3632/article/view/221182
- DOI: https://doi.org/10.1134/S1070363217080400
- ID: 221182
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Abstract
Dehydrocondensation reactions of silicon hydrides catalyzed by the rhodium(III) complex [RhCl3(Me2SO)3] in the absence of the second substrate were studied. It was found that the complex [RhCl3(Me2SO)3] catalyzed the dehydrocondensation reaction with the formation of compounds containing siloxane bonds. Analysis of NMR spectra has shown that the reaction of [RhCl3(Me2SO)3] with silicon hydride includes sequential desoxygenation of sulfoxide ligands to sulfide ligands with the complex [RhCl3(Me2S)3] formation.
About the authors
A. A. Eliseeva
St. Petersburg State Institute of Technology (Technical University)
Author for correspondence.
Email: nastya.shkinder@gmail.com
Russian Federation, Moskovskii pr. 26, St. Petersburg, 190013
E. G. Prudnikova
St. Petersburg State Institute of Technology (Technical University)
Email: nastya.shkinder@gmail.com
Russian Federation, Moskovskii pr. 26, St. Petersburg, 190013
T. L. Panikorovskii
St. Petersburg State University
Email: nastya.shkinder@gmail.com
Russian Federation, St. Petersburg
N. K. Skvortsov
St. Petersburg State Institute of Technology (Technical University)
Email: nastya.shkinder@gmail.com
Russian Federation, Moskovskii pr. 26, St. Petersburg, 190013
