Reactions of silicon hydrides catalyzed by rhodium(III) sulfoxide complexes
- Autores: Eliseeva A.1, Prudnikova E.1, Panikorovskii T.2, Skvortsov N.1
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Afiliações:
- St. Petersburg State Institute of Technology (Technical University)
- St. Petersburg State University
- Edição: Volume 87, Nº 8 (2017)
- Páginas: 1884-1886
- Seção: Letters to the Editor
- URL: https://journals.rcsi.science/1070-3632/article/view/221182
- DOI: https://doi.org/10.1134/S1070363217080400
- ID: 221182
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Resumo
Dehydrocondensation reactions of silicon hydrides catalyzed by the rhodium(III) complex [RhCl3(Me2SO)3] in the absence of the second substrate were studied. It was found that the complex [RhCl3(Me2SO)3] catalyzed the dehydrocondensation reaction with the formation of compounds containing siloxane bonds. Analysis of NMR spectra has shown that the reaction of [RhCl3(Me2SO)3] with silicon hydride includes sequential desoxygenation of sulfoxide ligands to sulfide ligands with the complex [RhCl3(Me2S)3] formation.
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Sobre autores
A. Eliseeva
St. Petersburg State Institute of Technology (Technical University)
Autor responsável pela correspondência
Email: nastya.shkinder@gmail.com
Rússia, Moskovskii pr. 26, St. Petersburg, 190013
E. Prudnikova
St. Petersburg State Institute of Technology (Technical University)
Email: nastya.shkinder@gmail.com
Rússia, Moskovskii pr. 26, St. Petersburg, 190013
T. Panikorovskii
St. Petersburg State University
Email: nastya.shkinder@gmail.com
Rússia, St. Petersburg
N. Skvortsov
St. Petersburg State Institute of Technology (Technical University)
Email: nastya.shkinder@gmail.com
Rússia, Moskovskii pr. 26, St. Petersburg, 190013