Multicomponent cyclothiomethylation of phenylenediamines and 4,4'-diaminodiphenyls with formaldehyde and 1,2-ethanedithiol
- Authors: Khabibullina G.R.1, Fedotova E.S.1, Anpilogova G.R.2, Akhmetova V.R.1, Ibragimov A.G.1
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Affiliations:
- Institute of Petrochemistry and Catalysis
- Ufa Institute of Chemistry
- Issue: Vol 86, No 7 (2016)
- Pages: 1608-1612
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/215656
- DOI: https://doi.org/10.1134/S1070363216070124
- ID: 215656
Cite item
Abstract
One-pot synthesis of bis-1,5,3-dithiazepanes by cyclothiomethylation of o-phenylenediamine, 4,4'-diaminodiphenyl, 4,4'-diaminodiphenyl oxide, and 4,4'-diaminodiphenylmethane with formaldehyde and 1,2- ethanedithiol was performed. Sorption properties of the newly synthesized bis[4-(1,5,3-dithiazepan-3-yl)-phenyl] oxide were investigated by the batch technique. High efficiency of the recovery of palladium(II) with this reagent from hydrochloric acid solutions at room temperature was shown.
About the authors
G. R. Khabibullina
Institute of Petrochemistry and Catalysis
Author for correspondence.
Email: ink@anrb.ru
Russian Federation, pr. Oktyabrya 141, Ufa, 450075
E. S. Fedotova
Institute of Petrochemistry and Catalysis
Email: ink@anrb.ru
Russian Federation, pr. Oktyabrya 141, Ufa, 450075
G. R. Anpilogova
Ufa Institute of Chemistry
Email: ink@anrb.ru
Russian Federation, Ufa
V. R. Akhmetova
Institute of Petrochemistry and Catalysis
Email: ink@anrb.ru
Russian Federation, pr. Oktyabrya 141, Ufa, 450075
A. G. Ibragimov
Institute of Petrochemistry and Catalysis
Email: ink@anrb.ru
Russian Federation, pr. Oktyabrya 141, Ufa, 450075