Reactions of 2-methyleneadamantane and 2-benzylideneadamantane with acetyl nitrate
- Authors: Krasnikov P.E.1, Osyanin V.A.1, Osipov D.V.1, Klimochkin Y.N.1
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Affiliations:
- Samara State Technical University
- Issue: Vol 86, No 2 (2016)
- Pages: 262-266
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/213683
- DOI: https://doi.org/10.1134/S1070363216020092
- ID: 213683
Cite item
Abstract
The reactions of 2-methylene- and 2-benzylideneadamantane with acetyl nitrate have been studied. In the case of 2-methyleneadamantane, the reaction proceeds via addition of nitronium cation at the double bond followed by stabilization of 2-nitromethyl-2-adamantyl carbocation. In the case of 2-benzylidenadamantane, ortho-substitution at the benzene ring occurred predominantly.
About the authors
P. E. Krasnikov
Samara State Technical University
Email: VOsyanin@mail.ru
Russian Federation, ul. Molodogvardeiskaya 244, Samara, 443100
V. A. Osyanin
Samara State Technical University
Author for correspondence.
Email: VOsyanin@mail.ru
Russian Federation, ul. Molodogvardeiskaya 244, Samara, 443100
D. V. Osipov
Samara State Technical University
Email: VOsyanin@mail.ru
Russian Federation, ul. Molodogvardeiskaya 244, Samara, 443100
Yu. N. Klimochkin
Samara State Technical University
Email: VOsyanin@mail.ru
Russian Federation, ul. Molodogvardeiskaya 244, Samara, 443100