Reactions of 2-methyleneadamantane and 2-benzylideneadamantane with acetyl nitrate
- 作者: Krasnikov P.1, Osyanin V.1, Osipov D.1, Klimochkin Y.1
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隶属关系:
- Samara State Technical University
- 期: 卷 86, 编号 2 (2016)
- 页面: 262-266
- 栏目: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/213683
- DOI: https://doi.org/10.1134/S1070363216020092
- ID: 213683
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详细
The reactions of 2-methylene- and 2-benzylideneadamantane with acetyl nitrate have been studied. In the case of 2-methyleneadamantane, the reaction proceeds via addition of nitronium cation at the double bond followed by stabilization of 2-nitromethyl-2-adamantyl carbocation. In the case of 2-benzylidenadamantane, ortho-substitution at the benzene ring occurred predominantly.
作者简介
P. Krasnikov
Samara State Technical University
Email: VOsyanin@mail.ru
俄罗斯联邦, ul. Molodogvardeiskaya 244, Samara, 443100
V. Osyanin
Samara State Technical University
编辑信件的主要联系方式.
Email: VOsyanin@mail.ru
俄罗斯联邦, ul. Molodogvardeiskaya 244, Samara, 443100
D. Osipov
Samara State Technical University
Email: VOsyanin@mail.ru
俄罗斯联邦, ul. Molodogvardeiskaya 244, Samara, 443100
Yu. Klimochkin
Samara State Technical University
Email: VOsyanin@mail.ru
俄罗斯联邦, ul. Molodogvardeiskaya 244, Samara, 443100