Luminescent Properties of Europium(III) Complexes with Quinaldic Acid and Sulfur–Containing Neutral Ligands
- Authors: Kalinovskaya I.V.1
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Affiliations:
- Institute of Chemistry
- Issue: Vol 89, No 12 (2019)
- Pages: 2420-2423
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/223201
- DOI: https://doi.org/10.1134/S1070363219120156
- ID: 223201
Cite item
Abstract
The luminescent heteroligand complexes of europium(III) with quinaldic acid and sulfur-containing neutral ligands Eu(Quin)3∙D∙3H2O (Quin–quinaldic acid, D–dimethyl sulfoxide or dihexyl sulfoxide) and Eu(Quin)3∙3H2O have been obtained. Their composition and structure have been determined. The thermal and spectral-luminescent properties of the heteroligand europium(III) complexes have been studied. The quinaldate ion has been found to coordinate to the europium(III) ion as a bidentate ligand. The Stark structure of 5D0–7Fj (j = 0, 1, 2) transitions in the low-temperature luminescence spectra of the europium(III) complexes has been analyzed
Keywords
About the authors
I. V. Kalinovskaya
Institute of Chemistry
Author for correspondence.
Email: kalinovskaya@ich.dvo.ru
Russian Federation, Vladivostok, 690022
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