Luminescent Properties of Europium(III) Complexes with Quinaldic Acid and Sulfur–Containing Neutral Ligands

Resumo

The luminescent heteroligand complexes of europium(III) with quinaldic acid and sulfur-containing neutral ligands Eu(Quin)₃∙D∙3H₂O (Quin–quinaldic acid, D–dimethyl sulfoxide or dihexyl sulfoxide) and Eu(Quin)₃∙3H₂O have been obtained. Their composition and structure have been determined. The thermal and spectral-luminescent properties of the heteroligand europium(III) complexes have been studied. The quinaldate ion has been found to coordinate to the europium(III) ion as a bidentate ligand. The Stark structure of ⁵D₀–⁷F_j (j = 0, 1, 2) transitions in the low-temperature luminescence spectra of the europium(III) complexes has been analyzed