Transesterification of Exocyclic Ester Group of Methyl Pheophorbide a


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Abstract

The reaction of methyl pheophorbide a with various alcohols in toluene in the presence of dimethylaminopyridine as a base was investigated. Under these conditions, a chemoselective transesterification of the exocyclic ring proceeds without the use of an activating agent (N-methyl-2-chloropyridinium iodide) or a catalyst (molecular iodine).

About the authors

L. A. Tulaeva

P. Sorokin Syktyvkar State University

Author for correspondence.
Email: tulaeva65@mail.ru
Russian Federation, Oktyabrskii pr. 55, Syktyvkar, 167001

N. V. Gileva

P. Sorokin Syktyvkar State University

Email: tulaeva65@mail.ru
Russian Federation, Oktyabrskii pr. 55, Syktyvkar, 167001

D. V. Belykh

Institute of Chemistry, Federal Research Center

Email: tulaeva65@mail.ru
Russian Federation, Syktyvkar


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