Transesterification of Exocyclic Ester Group of Methyl Pheophorbide a
- Authors: Tulaeva L.A.1, Gileva N.V.1, Belykh D.V.2
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Affiliations:
- P. Sorokin Syktyvkar State University
- Institute of Chemistry, Federal Research Center
- Issue: Vol 89, No 9 (2019)
- Pages: 1772-1776
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/223066
- DOI: https://doi.org/10.1134/S107036321909007X
- ID: 223066
Cite item
Abstract
The reaction of methyl pheophorbide a with various alcohols in toluene in the presence of dimethylaminopyridine as a base was investigated. Under these conditions, a chemoselective transesterification of the exocyclic ring proceeds without the use of an activating agent (N-methyl-2-chloropyridinium iodide) or a catalyst (molecular iodine).
About the authors
L. A. Tulaeva
P. Sorokin Syktyvkar State University
Author for correspondence.
Email: tulaeva65@mail.ru
Russian Federation, Oktyabrskii pr. 55, Syktyvkar, 167001
N. V. Gileva
P. Sorokin Syktyvkar State University
Email: tulaeva65@mail.ru
Russian Federation, Oktyabrskii pr. 55, Syktyvkar, 167001
D. V. Belykh
Institute of Chemistry, Federal Research Center
Email: tulaeva65@mail.ru
Russian Federation, Syktyvkar