Synthesis of 1,3,3,5,5-Penta[1-(2,2-dimethyl-1,3-dioxolan-4-yl)methoxy]-1-[(1H-1,2,3-triazol-4-yl)alkoxy]cyclotriphosphazenes
- Authors: Morgalyuk V.P.1, Strelkova T.S.1, Kononevich Y.N.1, Brel V.K.1
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Affiliations:
- A. N. Nesmeyanov Institute of Organoelement Compounds
- Issue: Vol 89, No 8 (2019)
- Pages: 1620-1624
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/223028
- DOI: https://doi.org/10.1134/S1070363219080115
- ID: 223028
Cite item
Abstract
Based on 1,3,3,5,5-penta[1-(2,2-dimethyl-1,3-dioxolan-4-yl)methoxy]-1-chlorocyclotriphosphazene, a series of hybrid compounds was obtained by two-step synthesis. In the molecules of the compounds obtained, hydrophobic organic residues are attached to the cyclotriphosphazene nucleus via a linker. A dialkyl substituted 1,2,3-triazole synthesized by click-chemistry methodology from acetylenic cyclotriphosphazene derivatives and organic azides in the presence of Cu(I) can be used as a linker connecting pentadioxolane-substituted phosphazene core. The reaction proceeds regioselectively with the formation of 1,4-disubstituted 1,2,3-triazoles only.
About the authors
V. P. Morgalyuk
A. N. Nesmeyanov Institute of Organoelement Compounds
Author for correspondence.
Email: morgaliuk@mail.ru
Russian Federation, ul. Vavilova 28, Moscow, 119991
T. S. Strelkova
A. N. Nesmeyanov Institute of Organoelement Compounds
Email: morgaliuk@mail.ru
Russian Federation, ul. Vavilova 28, Moscow, 119991
Yu. N. Kononevich
A. N. Nesmeyanov Institute of Organoelement Compounds
Email: morgaliuk@mail.ru
Russian Federation, ul. Vavilova 28, Moscow, 119991
V. K. Brel
A. N. Nesmeyanov Institute of Organoelement Compounds
Email: morgaliuk@mail.ru
Russian Federation, ul. Vavilova 28, Moscow, 119991