Synthesis of 1,3,3,5,5-Penta[1-(2,2-dimethyl-1,3-dioxolan-4-yl)methoxy]-1-[(1H-1,2,3-triazol-4-yl)alkoxy]cyclotriphosphazenes
- 作者: Morgalyuk V.1, Strelkova T.1, Kononevich Y.1, Brel V.1
-
隶属关系:
- A. N. Nesmeyanov Institute of Organoelement Compounds
- 期: 卷 89, 编号 8 (2019)
- 页面: 1620-1624
- 栏目: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/223028
- DOI: https://doi.org/10.1134/S1070363219080115
- ID: 223028
如何引用文章
详细
Based on 1,3,3,5,5-penta[1-(2,2-dimethyl-1,3-dioxolan-4-yl)methoxy]-1-chlorocyclotriphosphazene, a series of hybrid compounds was obtained by two-step synthesis. In the molecules of the compounds obtained, hydrophobic organic residues are attached to the cyclotriphosphazene nucleus via a linker. A dialkyl substituted 1,2,3-triazole synthesized by click-chemistry methodology from acetylenic cyclotriphosphazene derivatives and organic azides in the presence of Cu(I) can be used as a linker connecting pentadioxolane-substituted phosphazene core. The reaction proceeds regioselectively with the formation of 1,4-disubstituted 1,2,3-triazoles only.
作者简介
V. Morgalyuk
A. N. Nesmeyanov Institute of Organoelement Compounds
编辑信件的主要联系方式.
Email: morgaliuk@mail.ru
俄罗斯联邦, ul. Vavilova 28, Moscow, 119991
T. Strelkova
A. N. Nesmeyanov Institute of Organoelement Compounds
Email: morgaliuk@mail.ru
俄罗斯联邦, ul. Vavilova 28, Moscow, 119991
Yu. Kononevich
A. N. Nesmeyanov Institute of Organoelement Compounds
Email: morgaliuk@mail.ru
俄罗斯联邦, ul. Vavilova 28, Moscow, 119991
V. Brel
A. N. Nesmeyanov Institute of Organoelement Compounds
Email: morgaliuk@mail.ru
俄罗斯联邦, ul. Vavilova 28, Moscow, 119991