Catalytic Aminomethylation of Aminobenzamides with Bis(N,N-dimethylamino)methane and Carbamides


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Abstract

An effective method was developed for the synthesis of acyclic aniline derivatives bearing carbamide fragments by the reaction of carbamides with ortho-, meta-, and para-aminobenzamides and bis(N,N-dimethylamino) methane in the presence of NiCl2·6H2O and SmCl3·6H2O as catalysts.

About the authors

R. R. Khairullina

Institute of Petrochemistry and Catalysis of the Russian Academy of Sciences

Author for correspondence.
Email: ink@anrb.ru
Russian Federation, pr. Oktyabrya 141, Ufa, 450075

T. V. Tyumkina

Institute of Petrochemistry and Catalysis of the Russian Academy of Sciences

Email: ink@anrb.ru
Russian Federation, pr. Oktyabrya 141, Ufa, 450075

A. R. Geniyatova

Institute of Petrochemistry and Catalysis of the Russian Academy of Sciences

Email: ink@anrb.ru
Russian Federation, pr. Oktyabrya 141, Ufa, 450075

F. K. Mullagil’dina

Institute of Petrochemistry and Catalysis of the Russian Academy of Sciences

Email: ink@anrb.ru
Russian Federation, pr. Oktyabrya 141, Ufa, 450075

A. G. Ibragimov

Institute of Petrochemistry and Catalysis of the Russian Academy of Sciences

Email: ink@anrb.ru
Russian Federation, pr. Oktyabrya 141, Ufa, 450075


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