Catalytic Aminomethylation of Aminobenzamides with Bis( N , N -dimethylamino)methane and Carbamides

R. R. Khairullina; T. V. Tyumkina; A. R. Geniyatova; F. K. Mullagil’dina; A. G. Ibragimov

doi:10.1134/S1070363219020063

Catalytic Aminomethylation of Aminobenzamides with Bis(N,N-dimethylamino)methane and Carbamides

Autores: Khairullina R.¹, Tyumkina T.¹, Geniyatova A.¹, Mullagil’dina F.¹, Ibragimov A.¹
Afiliações:
1. Institute of Petrochemistry and Catalysis of the Russian Academy of Sciences
Edição: Volume 89, Nº 2 (2019)
Páginas: 204-211
Seção: Article
URL: https://journals.rcsi.science/1070-3632/article/view/222739
DOI: https://doi.org/10.1134/S1070363219020063
ID: 222739

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An effective method was developed for the synthesis of acyclic aniline derivatives bearing carbamide fragments by the reaction of carbamides with ortho-, meta-, and para-aminobenzamides and bis(N,N-dimethylamino) methane in the presence of NiCl₂·6H₂O and SmCl₃·6H₂O as catalysts.