Synthesis of Bisthiacalix[4]arene: Reaction of Piperazine with Monoacrylamide Derivative of p-tert-Butylthiacalix[4]arene
- Authors: Nosov R.V.1, Stoikov I.I.1
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Affiliations:
- Butlerov Chemical Institute
- Issue: Vol 88, No 11 (2018)
- Pages: 2314-2320
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/222532
- DOI: https://doi.org/10.1134/S1070363218110117
- ID: 222532
Cite item
Abstract
The reaction of acryloyl chloride with the monoamine derivative of p-tert-butylthiacalix[4]arene was used to synthesize p-tert-butylthiacalix[4]arene monoacrylamide in the 1,3-alternate conformation. The effect of the nature of the amine on the result of its Michael reaction with the synthesized p-tert-butylthiacalix[4]arene monoacrylamide was studied. The latter was reacted with piperazine to obtain bisthiacalix[4]arene with the macrocyclic fragments in the 1,3-alternate conformation.
About the authors
R. V. Nosov
Butlerov Chemical Institute
Email: ivan.stoikov@mail.ru
Russian Federation, ul. Kremlevskaya 18, Kazan, Tatarstan, 420008
I. I. Stoikov
Butlerov Chemical Institute
Author for correspondence.
Email: ivan.stoikov@mail.ru
Russian Federation, ul. Kremlevskaya 18, Kazan, Tatarstan, 420008