Email this article Influence of Solvents on the Rate of Thermal Decomposition of Peroxydecanoic Acid
- Authors: Dutka V.S.1, Midyana G.G.2, Dutka Y.V.1, Pal’chikova E.Y.3
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Affiliations:
- Ivan Franko National University of Lviv
- Department of Physical Chemistry of Fossil Fuels, Litvinenko Institute of Physical Organic and Coal Chemistry
- Institute of Geology and Geochemistry of Fossil Fuels
- Issue: Vol 88, No 2 (2018)
- Pages: 188-194
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/221981
- DOI: https://doi.org/10.1134/S1070363218020020
- ID: 221981
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Abstract
Thermal decomposition of peroxydecanoic acid has been investigated in various organic solvents. The reaction medium significantly affects the rate of peroxydecanoic acid thermal decomposition. It has been shown that primary homolytic decomposition of peroxy group is followed by induced radical chain decomposition reactions. The solvent nature influences both primary homolytic decomposition and secondary induced reactions. The correlation equations relating kinetic parameters of peroxydecanoic acid thermolysis and basic solvent properties have been derived.
About the authors
V. S. Dutka
Ivan Franko National University of Lviv
Author for correspondence.
Email: vdutka@ukr.net
Ukraine, ul. Universitetskaya 1, Lviv
G. G. Midyana
Department of Physical Chemistry of Fossil Fuels, Litvinenko Institute of Physical Organic and Coal Chemistry
Email: vdutka@ukr.net
Ukraine, Lviv
Yu. V. Dutka
Ivan Franko National University of Lviv
Email: vdutka@ukr.net
Ukraine, ul. Universitetskaya 1, Lviv
E. Ya. Pal’chikova
Institute of Geology and Geochemistry of Fossil Fuels
Email: vdutka@ukr.net
Ukraine, Lviv
