Influence of Solvents on the Rate of Thermal Decomposition of Peroxydecanoic Acid
- 作者: Dutka V.1, Midyana G.2, Dutka Y.1, Pal’chikova E.3
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隶属关系:
- Ivan Franko National University of Lviv
- Department of Physical Chemistry of Fossil Fuels, Litvinenko Institute of Physical Organic and Coal Chemistry
- Institute of Geology and Geochemistry of Fossil Fuels
- 期: 卷 88, 编号 2 (2018)
- 页面: 188-194
- 栏目: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/221981
- DOI: https://doi.org/10.1134/S1070363218020020
- ID: 221981
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详细
Thermal decomposition of peroxydecanoic acid has been investigated in various organic solvents. The reaction medium significantly affects the rate of peroxydecanoic acid thermal decomposition. It has been shown that primary homolytic decomposition of peroxy group is followed by induced radical chain decomposition reactions. The solvent nature influences both primary homolytic decomposition and secondary induced reactions. The correlation equations relating kinetic parameters of peroxydecanoic acid thermolysis and basic solvent properties have been derived.
作者简介
V. Dutka
Ivan Franko National University of Lviv
编辑信件的主要联系方式.
Email: vdutka@ukr.net
乌克兰, ul. Universitetskaya 1, Lviv
G. Midyana
Department of Physical Chemistry of Fossil Fuels, Litvinenko Institute of Physical Organic and Coal Chemistry
Email: vdutka@ukr.net
乌克兰, Lviv
Yu. Dutka
Ivan Franko National University of Lviv
Email: vdutka@ukr.net
乌克兰, ul. Universitetskaya 1, Lviv
E. Pal’chikova
Institute of Geology and Geochemistry of Fossil Fuels
Email: vdutka@ukr.net
乌克兰, Lviv