On the possibility of homolytic addition of N-bromohexamethyldisilazane to the triple carbon–carbon bond


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Abstract

By an example of a reaction of N-bromohexamethyldisilazane with phenylacetylene the possibility of its homolytic addition to the triple carbon-carbon bond with the formation of a mixture of the corresponding E- and Z-isomers in the ratio of 1.2 : 1 was shown.

About the authors

V. I. Rakhlin

A.E. Favorskii Irkutsk Institute of Chemistry, Siberian Branch

Author for correspondence.
Email: vir@irioch.irk.ru
Russian Federation, ul. Favorskogo 1, Irkutsk, 664033

I. P. Tsyrendorzhieva

A.E. Favorskii Irkutsk Institute of Chemistry, Siberian Branch

Email: vir@irioch.irk.ru
Russian Federation, ul. Favorskogo 1, Irkutsk, 664033

A. I. Albanov

A.E. Favorskii Irkutsk Institute of Chemistry, Siberian Branch

Email: vir@irioch.irk.ru
Russian Federation, ul. Favorskogo 1, Irkutsk, 664033


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