On the possibility of homolytic addition of N-bromohexamethyldisilazane to the triple carbon–carbon bond
- Authors: Rakhlin V.I.1, Tsyrendorzhieva I.P.1, Albanov A.I.1
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Affiliations:
- A.E. Favorskii Irkutsk Institute of Chemistry, Siberian Branch
- Issue: Vol 87, No 4 (2017)
- Pages: 880-881
- Section: Letters to the Editor
- URL: https://journals.rcsi.science/1070-3632/article/view/219599
- DOI: https://doi.org/10.1134/S1070363217040351
- ID: 219599
Cite item
Abstract
By an example of a reaction of N-bromohexamethyldisilazane with phenylacetylene the possibility of its homolytic addition to the triple carbon-carbon bond with the formation of a mixture of the corresponding E- and Z-isomers in the ratio of 1.2 : 1 was shown.
About the authors
V. I. Rakhlin
A.E. Favorskii Irkutsk Institute of Chemistry, Siberian Branch
Author for correspondence.
Email: vir@irioch.irk.ru
Russian Federation, ul. Favorskogo 1, Irkutsk, 664033
I. P. Tsyrendorzhieva
A.E. Favorskii Irkutsk Institute of Chemistry, Siberian Branch
Email: vir@irioch.irk.ru
Russian Federation, ul. Favorskogo 1, Irkutsk, 664033
A. I. Albanov
A.E. Favorskii Irkutsk Institute of Chemistry, Siberian Branch
Email: vir@irioch.irk.ru
Russian Federation, ul. Favorskogo 1, Irkutsk, 664033