Nucleophilic substitution in 4-bromo-5-nitrophthalonitrile: XIV. Synthesis and properties of 4,5-bis[4-(1-methyl-1-phenylethyl)phenoxy]phthalonitrile and phthalocyanines therefrom

S. A. Znoiko; M. A. Serova; A. A. Uspenskaya; A. V. Zav’yalov; V. E. Maizlish; G. P. Shaposhnikov

doi:10.1134/S1070363216110165

Nucleophilic substitution in 4-bromo-5-nitrophthalonitrile: XIV. Synthesis and properties of 4,5-bis[4-(1-methyl-1-phenylethyl)phenoxy]phthalonitrile and phthalocyanines therefrom

Authors: Znoiko S.A.¹, Serova M.A.¹, Uspenskaya A.A.¹, Zav’yalov A.V.¹, Maizlish V.E.¹, Shaposhnikov G.P.¹
Affiliations:
1. Research Institute of Macroheterocyclic Chemistry
Issue: Vol 86, No 11 (2016)
Pages: 2501-2507
Section: Article
URL: https://journals.rcsi.science/1070-3632/article/view/216550
DOI: https://doi.org/10.1134/S1070363216110165
ID: 216550

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Abstract

4,5-Bis[4-(1-methyl-1-phenylethyl)phenoxy]phthalonitrile was prepared by the nucleophilic substitution of the nitro group and bromine in 4-bromo-5-nitrophathalonitrile. The product was used to synthesize the corresponding octasubstituted phthalocyanine, as well as its magnesium, copper, zinc, cobalt, and nickel complexes. The spectral properties of the synthesized phthalocyanines were studied.