Email this article Synthesis and structure of platinum complexes [Bu4P][PtBr6] and [Bu4P][PtBr5(DMSO-S)]
- Authors: Sharutin V.V.1, Sharutina O.K.1, Senchurin V.S.1
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Affiliations:
- South Ural National Research State University
- Issue: Vol 86, No 9 (2016)
- Pages: 2100-2104
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/216193
- DOI: https://doi.org/10.1134/S1070363216090206
- ID: 216193
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Abstract
By the reaction of tetrabutylphosphonium bromide with potassium hexabromoplatinate (2: 1, mol) in acetone complex [Bu4P]2[PtBr6] was obtained, which after crystallization from dimethyl sulfoxide gave complex [Bu4P][PtBr5(DMSO-S)]. Phosphorus atoms in both complexes have tetrahedral surrounding.
About the authors
V. V. Sharutin
South Ural National Research State University
Author for correspondence.
Email: vvsharutin@rambler.ru
Russian Federation, pr. Lenina 76, Chelyabinsk, 454080
O. K. Sharutina
South Ural National Research State University
Email: vvsharutin@rambler.ru
Russian Federation, pr. Lenina 76, Chelyabinsk, 454080
V. S. Senchurin
South Ural National Research State University
Email: vvsharutin@rambler.ru
Russian Federation, pr. Lenina 76, Chelyabinsk, 454080
