Email this article Synthesis and photoluminescence of the solid phases of the binary system of mixed-ligand Eu(III) and Tb(III) dithiophosphinate complexes
- Authors: Bryleva Y.A.1, Rakhmanova M.I.1, Korol’kov I.V.1,2, Tsygankova A.R.1,2, Larionov S.V.1,2
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Affiliations:
- Nikolaev Institute of Inorganic Chemistry, Siberian Branch
- Novosibirsk State University
- Issue: Vol 86, No 9 (2016)
- Pages: 2095-2099
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/216185
- DOI: https://doi.org/10.1134/S107036321609019X
- ID: 216185
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Abstract
Solid phases of the [Eu(Phen)(i-Bu2PS2)2(NO3)]–[Tb(Phen)(i-Bu2PS2)2(NO3)] binary system are synthesized. The results of X-ray diffraction phase analysis and photoluminescence measurements allow the synthesized isostructural phases to be classed with substitutional solid solutions. The photoluminescence measurements revealed Tb(III)→Eu(III) energy transfer which induces Eu3+ luminescence.
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About the authors
Yu. A. Bryleva
Nikolaev Institute of Inorganic Chemistry, Siberian Branch
Author for correspondence.
Email: tapzu_bryleva@mail.ru
Russian Federation, pr. Akademika Lavrent’eva 3, Novosibirsk, 630090
M. I. Rakhmanova
Nikolaev Institute of Inorganic Chemistry, Siberian Branch
Email: tapzu_bryleva@mail.ru
Russian Federation, pr. Akademika Lavrent’eva 3, Novosibirsk, 630090
I. V. Korol’kov
Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Novosibirsk State University
Email: tapzu_bryleva@mail.ru
Russian Federation, pr. Akademika Lavrent’eva 3, Novosibirsk, 630090; Novosibirsk
A. R. Tsygankova
Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Novosibirsk State University
Email: tapzu_bryleva@mail.ru
Russian Federation, pr. Akademika Lavrent’eva 3, Novosibirsk, 630090; Novosibirsk
S. V. Larionov
Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Novosibirsk State University
Email: tapzu_bryleva@mail.ru
Russian Federation, pr. Akademika Lavrent’eva 3, Novosibirsk, 630090; Novosibirsk
