Email this article Synthesis and properties of manganese complexes of meso-tetraphenyltetrabenzoporphyrin
- Authors: Chizhova N.V.1, Mal’tseva O.V.1, Mamardashvili N.Z.1
-
Affiliations:
- Krestov Institute of Solutions Chemistry
- Issue: Vol 86, No 8 (2016)
- Pages: 1907-1911
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/215981
- DOI: https://doi.org/10.1134/S1070363216080211
- ID: 215981
Cite item
Open Access
Access granted
Subscription Access
Abstract
The coordination of meso-tetraphenyltetrabenzoporphyrin and metal exchange of its Cd(II) complex with manganese(II) chloride and acetate in DMF and a chloroform–methanol mixture have been studied by spectrophotometry. The Mn(III) chloride and acetate acido complexes formed in these reactions have been isolated and characterized. The dissolution of the synthesized complexes in DMF in the presence of solid KOH gives Mn(II) meso-tetraphenyltetrabenzoporphyrinate.
About the authors
N. V. Chizhova
Krestov Institute of Solutions Chemistry
Author for correspondence.
Email: nvc@isc-ras.ru
Russian Federation, ul. Akademicheskaya 1, Ivanovo, 153040
O. V. Mal’tseva
Krestov Institute of Solutions Chemistry
Email: nvc@isc-ras.ru
Russian Federation, ul. Akademicheskaya 1, Ivanovo, 153040
N. Zh. Mamardashvili
Krestov Institute of Solutions Chemistry
Email: nvc@isc-ras.ru
Russian Federation, ul. Akademicheskaya 1, Ivanovo, 153040
