Synthesis and properties of manganese complexes of meso-tetraphenyltetrabenzoporphyrin
- Autores: Chizhova N.1, Mal’tseva O.1, Mamardashvili N.1
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Afiliações:
- Krestov Institute of Solutions Chemistry
- Edição: Volume 86, Nº 8 (2016)
- Páginas: 1907-1911
- Seção: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/215981
- DOI: https://doi.org/10.1134/S1070363216080211
- ID: 215981
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Resumo
The coordination of meso-tetraphenyltetrabenzoporphyrin and metal exchange of its Cd(II) complex with manganese(II) chloride and acetate in DMF and a chloroform–methanol mixture have been studied by spectrophotometry. The Mn(III) chloride and acetate acido complexes formed in these reactions have been isolated and characterized. The dissolution of the synthesized complexes in DMF in the presence of solid KOH gives Mn(II) meso-tetraphenyltetrabenzoporphyrinate.
Sobre autores
N. Chizhova
Krestov Institute of Solutions Chemistry
Autor responsável pela correspondência
Email: nvc@isc-ras.ru
Rússia, ul. Akademicheskaya 1, Ivanovo, 153040
O. Mal’tseva
Krestov Institute of Solutions Chemistry
Email: nvc@isc-ras.ru
Rússia, ul. Akademicheskaya 1, Ivanovo, 153040
N. Mamardashvili
Krestov Institute of Solutions Chemistry
Email: nvc@isc-ras.ru
Rússia, ul. Akademicheskaya 1, Ivanovo, 153040