Email this article Kinetic features of radical polymerization of styrene under microwave irradiation conditions
- Authors: Mudrov A.N.1, Tishchenko A.S.1, Ageeva T.A.1, Koifman O.I.1,2
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Affiliations:
- Ivanovo State University of Chemical Technology
- Krestov Institute of Solution Chemistry
- Issue: Vol 86, No 6 (2016)
- Pages: 1510-1514
- Section: Selected articles originally published in Russian in Rossiiskii Khimicheskii Zhurnal (Russian Chemistry Journal)
- URL: https://journals.rcsi.science/1070-3632/article/view/215576
- DOI: https://doi.org/10.1134/S1070363216060487
- ID: 215576
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Abstract
A comparative study of radical polymerization of styrene under thermal and microwave heating conditions has been carried out. The polymerization reaction orders with respect to the monomer and initiator concentrations and the polymerization rate constants have been determined. It has been found that non-thermal microwave effects are not manifested during styrene polymerization, because styrene is a weakly polar substance.
About the authors
A. N. Mudrov
Ivanovo State University of Chemical Technology
Author for correspondence.
Email: mudrovan@mail.ru
Russian Federation, Sheremetevskii pr. 7, Ivanovo, 153000
A. S. Tishchenko
Ivanovo State University of Chemical Technology
Email: mudrovan@mail.ru
Russian Federation, Sheremetevskii pr. 7, Ivanovo, 153000
T. A. Ageeva
Ivanovo State University of Chemical Technology
Email: mudrovan@mail.ru
Russian Federation, Sheremetevskii pr. 7, Ivanovo, 153000
O. I. Koifman
Ivanovo State University of Chemical Technology; Krestov Institute of Solution Chemistry
Email: mudrovan@mail.ru
Russian Federation, Sheremetevskii pr. 7, Ivanovo, 153000; ul. Akademicheskaya 1, Ivanovo, 153045
