Kinetic features of radical polymerization of styrene under microwave irradiation conditions
- Autores: Mudrov A.1, Tishchenko A.1, Ageeva T.1, Koifman O.1,2
-
Afiliações:
- Ivanovo State University of Chemical Technology
- Krestov Institute of Solution Chemistry
- Edição: Volume 86, Nº 6 (2016)
- Páginas: 1510-1514
- Seção: Selected articles originally published in Russian in Rossiiskii Khimicheskii Zhurnal (Russian Chemistry Journal)
- URL: https://journals.rcsi.science/1070-3632/article/view/215576
- DOI: https://doi.org/10.1134/S1070363216060487
- ID: 215576
Citar
Resumo
A comparative study of radical polymerization of styrene under thermal and microwave heating conditions has been carried out. The polymerization reaction orders with respect to the monomer and initiator concentrations and the polymerization rate constants have been determined. It has been found that non-thermal microwave effects are not manifested during styrene polymerization, because styrene is a weakly polar substance.
Sobre autores
A. Mudrov
Ivanovo State University of Chemical Technology
Autor responsável pela correspondência
Email: mudrovan@mail.ru
Rússia, Sheremetevskii pr. 7, Ivanovo, 153000
A. Tishchenko
Ivanovo State University of Chemical Technology
Email: mudrovan@mail.ru
Rússia, Sheremetevskii pr. 7, Ivanovo, 153000
T. Ageeva
Ivanovo State University of Chemical Technology
Email: mudrovan@mail.ru
Rússia, Sheremetevskii pr. 7, Ivanovo, 153000
O. Koifman
Ivanovo State University of Chemical Technology; Krestov Institute of Solution Chemistry
Email: mudrovan@mail.ru
Rússia, Sheremetevskii pr. 7, Ivanovo, 153000; ul. Akademicheskaya 1, Ivanovo, 153045