Email this article Interaction of nitrogen-containing propargyl compounds with CH-acids in the presence of mercury(II) acetate
- Authors: Hobosyan N.G.1,2, Balyan K.V.1, Nersisyan H.S.1, Sargsyan H.B.1, Chobanyan Z.A.1
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Affiliations:
- Institute of Organic Chemistry, Scientific Technological Center of Organic and Pharmaceutical Chemistry
- Kh. Abovian Armenian State Pedagogical University
- Issue: Vol 86, No 5 (2016)
- Pages: 1011-1016
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/214902
- DOI: https://doi.org/10.1134/S1070363216050042
- ID: 214902
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Abstract
Regiochemistry of the reaction of nitrogen-containing propargyl compounds with CH-acids in the presence of mercury(II) acetate has been studied. The possibility of alkylation at the substituted carbon atom of the triple bond of the nitrogen-containing propargyl compounds by sodium salts of acetylacetone and acetoacetic ester with the formation of prototropic isomers has been shown.
About the authors
N. G. Hobosyan
Institute of Organic Chemistry, Scientific Technological Center of Organic and Pharmaceutical Chemistry; Kh. Abovian Armenian State Pedagogical University
Author for correspondence.
Email: ninahobosyan@mail.ru
Armenia, pr. Azatutyan 26, Yerevan, 0014; Yerevan
K. V. Balyan
Institute of Organic Chemistry, Scientific Technological Center of Organic and Pharmaceutical Chemistry
Email: ninahobosyan@mail.ru
Armenia, pr. Azatutyan 26, Yerevan, 0014
H. S. Nersisyan
Institute of Organic Chemistry, Scientific Technological Center of Organic and Pharmaceutical Chemistry
Email: ninahobosyan@mail.ru
Armenia, pr. Azatutyan 26, Yerevan, 0014
H. B. Sargsyan
Institute of Organic Chemistry, Scientific Technological Center of Organic and Pharmaceutical Chemistry
Email: ninahobosyan@mail.ru
Armenia, pr. Azatutyan 26, Yerevan, 0014
Zh. A. Chobanyan
Institute of Organic Chemistry, Scientific Technological Center of Organic and Pharmaceutical Chemistry
Email: ninahobosyan@mail.ru
Armenia, pr. Azatutyan 26, Yerevan, 0014
