Interaction of nitrogen-containing propargyl compounds with CH-acids in the presence of mercury(II) acetate


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Regiochemistry of the reaction of nitrogen-containing propargyl compounds with CH-acids in the presence of mercury(II) acetate has been studied. The possibility of alkylation at the substituted carbon atom of the triple bond of the nitrogen-containing propargyl compounds by sodium salts of acetylacetone and acetoacetic ester with the formation of prototropic isomers has been shown.

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N. Hobosyan

Institute of Organic Chemistry, Scientific Technological Center of Organic and Pharmaceutical Chemistry; Kh. Abovian Armenian State Pedagogical University

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Email: ninahobosyan@mail.ru
亚美尼亚, pr. Azatutyan 26, Yerevan, 0014; Yerevan

K. Balyan

Institute of Organic Chemistry, Scientific Technological Center of Organic and Pharmaceutical Chemistry

Email: ninahobosyan@mail.ru
亚美尼亚, pr. Azatutyan 26, Yerevan, 0014

H. Nersisyan

Institute of Organic Chemistry, Scientific Technological Center of Organic and Pharmaceutical Chemistry

Email: ninahobosyan@mail.ru
亚美尼亚, pr. Azatutyan 26, Yerevan, 0014

H. Sargsyan

Institute of Organic Chemistry, Scientific Technological Center of Organic and Pharmaceutical Chemistry

Email: ninahobosyan@mail.ru
亚美尼亚, pr. Azatutyan 26, Yerevan, 0014

Zh. Chobanyan

Institute of Organic Chemistry, Scientific Technological Center of Organic and Pharmaceutical Chemistry

Email: ninahobosyan@mail.ru
亚美尼亚, pr. Azatutyan 26, Yerevan, 0014


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