Email this article Colloid and nanosized catalysts in organic synthesis: XII. Hydrogenation of carbonitriles catalyzed by nickel nanoparticles
- Authors: Mokhov V.M.1, Popov Y.V.1, Shcherbakova K.V.1
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Affiliations:
- Volgograd State Technical University
- Issue: Vol 86, No 2 (2016)
- Pages: 273-280
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/213697
- DOI: https://doi.org/10.1134/S1070363216020110
- ID: 213697
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Abstract
Hydrogenation of carbonitriles catalyzed by nickel nanoparticles in isopropanol proceeds under atmospheric pressure of hydrogen within 6–15 h to yield mainly secondary amines. Hydrogenation of α-aminonitriles results in reductive decyanation. β-Aminonitriles undergo hydrogenolysis at the nitrogen–carbon bond.
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About the authors
V. M. Mokhov
Volgograd State Technical University
Author for correspondence.
Email: tons@vstu.ru
Russian Federation, pr. Lenina 28, Volgograd, 400131
Yu. V. Popov
Volgograd State Technical University
Email: tons@vstu.ru
Russian Federation, pr. Lenina 28, Volgograd, 400131
K. V. Shcherbakova
Volgograd State Technical University
Email: tons@vstu.ru
Russian Federation, pr. Lenina 28, Volgograd, 400131
