Colloid and nanosized catalysts in organic synthesis: XII. Hydrogenation of carbonitriles catalyzed by nickel nanoparticles
- 作者: Mokhov V.1, Popov Y.1, Shcherbakova K.1
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隶属关系:
- Volgograd State Technical University
- 期: 卷 86, 编号 2 (2016)
- 页面: 273-280
- 栏目: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/213697
- DOI: https://doi.org/10.1134/S1070363216020110
- ID: 213697
如何引用文章
详细
Hydrogenation of carbonitriles catalyzed by nickel nanoparticles in isopropanol proceeds under atmospheric pressure of hydrogen within 6–15 h to yield mainly secondary amines. Hydrogenation of α-aminonitriles results in reductive decyanation. β-Aminonitriles undergo hydrogenolysis at the nitrogen–carbon bond.
作者简介
V. Mokhov
Volgograd State Technical University
编辑信件的主要联系方式.
Email: tons@vstu.ru
俄罗斯联邦, pr. Lenina 28, Volgograd, 400131
Yu. Popov
Volgograd State Technical University
Email: tons@vstu.ru
俄罗斯联邦, pr. Lenina 28, Volgograd, 400131
K. Shcherbakova
Volgograd State Technical University
Email: tons@vstu.ru
俄罗斯联邦, pr. Lenina 28, Volgograd, 400131