Email this article Spectrophotometric study of dehalogenation of benzyl halides with nickel in aprotic dipolar solvents in the presence of oxygen
- Authors: Egorov А.М.1, Novikova А.N.2, Stepanova Е.V.1
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Affiliations:
- Tula State University
- FSBI “Tula Interregional Veterinary Laboratory,”
- Issue: Vol 86, No 2 (2016)
- Pages: 251-255
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/213669
- DOI: https://doi.org/10.1134/S1070363216020079
- ID: 213669
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Abstract
Oxidative dissolution of nickel in the benzyl halogenide – dipolar aprotic solvent system in the presence of air oxygen proceeds with the formation of benzaldehyde, benzyl alcohol, 1,2-diphenylethane, and trace amounts of 4,4'-ditolyl. Spectrophotometry studies have revealed that the oxidation products are formed in the solution rather than at the nickel surface. It has been shown that the oxygen adsorbed at the nickel surface practically does not pass into the solution.
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About the authors
А. М. Egorov
Tula State University
Email: stepanova_ev@yahoo.com
Russian Federation, pr. Lenina 92, Tula, 300600
А. N. Novikova
FSBI “Tula Interregional Veterinary Laboratory,”
Email: stepanova_ev@yahoo.com
Russian Federation, Tula
Е. V. Stepanova
Tula State University
Author for correspondence.
Email: stepanova_ev@yahoo.com
Russian Federation, pr. Lenina 92, Tula, 300600
