Spectrophotometric study of dehalogenation of benzyl halides with nickel in aprotic dipolar solvents in the presence of oxygen
- 作者: Egorov А.1, Novikova А.2, Stepanova Е.1
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隶属关系:
- Tula State University
- FSBI “Tula Interregional Veterinary Laboratory,”
- 期: 卷 86, 编号 2 (2016)
- 页面: 251-255
- 栏目: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/213669
- DOI: https://doi.org/10.1134/S1070363216020079
- ID: 213669
如何引用文章
详细
Oxidative dissolution of nickel in the benzyl halogenide – dipolar aprotic solvent system in the presence of air oxygen proceeds with the formation of benzaldehyde, benzyl alcohol, 1,2-diphenylethane, and trace amounts of 4,4'-ditolyl. Spectrophotometry studies have revealed that the oxidation products are formed in the solution rather than at the nickel surface. It has been shown that the oxygen adsorbed at the nickel surface practically does not pass into the solution.
作者简介
А. Egorov
Tula State University
Email: stepanova_ev@yahoo.com
俄罗斯联邦, pr. Lenina 92, Tula, 300600
А. Novikova
FSBI “Tula Interregional Veterinary Laboratory,”
Email: stepanova_ev@yahoo.com
俄罗斯联邦, Tula
Е. Stepanova
Tula State University
编辑信件的主要联系方式.
Email: stepanova_ev@yahoo.com
俄罗斯联邦, pr. Lenina 92, Tula, 300600
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