Synthesis of substituted fulvenes with inden-2-ylphosphonic acid fragments
- 作者: Prishchenko A.1, Livantsov M.1, Novikova O.1, Livantsova L.1, Petrosyan V.1
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隶属关系:
- Department of Chemistry, M. V. Lomonosov Moscow State University
- 期: 卷 66, 编号 7 (2017)
- 页面: 1261-1264
- 栏目: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/240965
- DOI: https://doi.org/10.1007/s11172-017-1882-9
- ID: 240965
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详细
We have developed preparative methods for the synthesis of substituted fulvenes including inden-2-ylphosphonic acid fragments, as well as aromatic and heterocyclic substituents, based on bis(trimethylsilyl)inden-2-ylphosphonate and substituted azomethines in the presence of sodium hydride as an efficient initiator of the reaction. Subsequent treatment of the phosphonates with methanolic solution of sodium methoxide furnished water-soluble disodium salts of the corresponding phosphonic acids.
作者简介
A. Prishchenko
Department of Chemistry, M. V. Lomonosov Moscow State University
编辑信件的主要联系方式.
Email: aprishchenko@yandex.ru
俄罗斯联邦, Build. 3, 1 Leninskie Gory, Moscow, 119991
M. Livantsov
Department of Chemistry, M. V. Lomonosov Moscow State University
Email: aprishchenko@yandex.ru
俄罗斯联邦, Build. 3, 1 Leninskie Gory, Moscow, 119991
O. Novikova
Department of Chemistry, M. V. Lomonosov Moscow State University
Email: aprishchenko@yandex.ru
俄罗斯联邦, Build. 3, 1 Leninskie Gory, Moscow, 119991
L. Livantsova
Department of Chemistry, M. V. Lomonosov Moscow State University
Email: aprishchenko@yandex.ru
俄罗斯联邦, Build. 3, 1 Leninskie Gory, Moscow, 119991
V. Petrosyan
Department of Chemistry, M. V. Lomonosov Moscow State University
Email: aprishchenko@yandex.ru
俄罗斯联邦, Build. 3, 1 Leninskie Gory, Moscow, 119991