Synthesis of substituted fulvenes with inden-2-ylphosphonic acid fragments

A. A. Prishchenko; M. V. Livantsov; O. P. Novikova; L. I. Livantsova; V. S. Petrosyan

doi:10.1007/s11172-017-1882-9

Synthesis of substituted fulvenes with inden-2-ylphosphonic acid fragments

Авторлар: Prishchenko A.¹, Livantsov M.¹, Novikova O.¹, Livantsova L.¹, Petrosyan V.¹
Мекемелер:
1. Department of Chemistry, M. V. Lomonosov Moscow State University
Шығарылым: Том 66, № 7 (2017)
Беттер: 1261-1264
Бөлім: Full Articles
URL: https://journals.rcsi.science/1066-5285/article/view/240965
DOI: https://doi.org/10.1007/s11172-017-1882-9
ID: 240965

Дәйексөз келтіру

Толық мәтін

Ашық рұқсат
Рұқсат жабық

Рұқсат берілді
Рұқсат жабық

Тек жазылушылар үшін

Аннотация
Авторлар туралы
Әдебиет тізімі
Статистика

Аннотация

We have developed preparative methods for the synthesis of substituted fulvenes including inden-2-ylphosphonic acid fragments, as well as aromatic and heterocyclic substituents, based on bis(trimethylsilyl)inden-2-ylphosphonate and substituted azomethines in the presence of sodium hydride as an efficient initiator of the reaction. Subsequent treatment of the phosphonates with methanolic solution of sodium methoxide furnished water-soluble disodium salts of the corresponding phosphonic acids.