Synthesis of N-nitro-N′-(trimethylsilyl)carbodiimide
- Autores: Churakov A.1, Ioffe S.1, Voronin A.1, Tartakovsky V.1
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Afiliações:
- N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
- Edição: Volume 66, Nº 6 (2017)
- Páginas: 991-994
- Seção: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/240691
- DOI: https://doi.org/10.1007/s11172-017-1844-2
- ID: 240691
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Resumo
Nitration of N,N′-bis(trimethylsilyl)carbodiimide with N2O5 or (NO2)2SiF6 afforded N-nitro-N´-(trimethylsilyl)carbodiimide, the first representative of N-nitro carbodiimides. Its further nitration led to the release of CO2, which is presumably formed in the course of N,N´-dinitrocarbodiimide decomposition. The reactions of N-nitro-N´-(trimethylsilyl)carbodiimide with nucleophiles take place both at the tri methylsilyl group (for example, with NH3) to give nitrocyanamide salts and at the carbodiimide C atom (for example, with Et2NH) to give the corresponding nitroguan idines.
Sobre autores
A. Churakov
N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
Autor responsável pela correspondência
Email: churakov@ioc.ac.ru
Rússia, 47 Leninsky prosp., Moscow, 119991
S. Ioffe
N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
Email: churakov@ioc.ac.ru
Rússia, 47 Leninsky prosp., Moscow, 119991
A. Voronin
N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
Email: churakov@ioc.ac.ru
Rússia, 47 Leninsky prosp., Moscow, 119991
V. Tartakovsky
N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
Email: churakov@ioc.ac.ru
Rússia, 47 Leninsky prosp., Moscow, 119991