Enviar artigo por via de e-mail Oxidation of 2,3,6-trimethylphenol to 2,3,5-trimethyl-1,4-benzoquinon over binary xerogels TiO2—SiO2 in the three-phase system
- Autores: Mikushina Y.1, Shishmakov A.1, Petro L.1
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Afiliações:
- I. Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences
- Edição: Volume 66, Nº 4 (2017)
- Páginas: 677-682
- Seção: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/240416
- DOI: https://doi.org/10.1007/s11172-017-1791-y
- ID: 240416
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Resumo
The technique of synthesis of 2,3,5-trimethyl-1,4-benzoquinon via catalytic oxidation of 2,3,6-trimethylphenol in H2O2—H2O—PhCH3 system with vibrational stirring is developed. Xerogels TiO2 and TiO2—SiO2 were used as catalysts in the process. The effect of physicochemical properties of xerogels on the course and characteristics of oxidation is studied.
Sobre autores
Yu. Mikushina
I. Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences
Autor responsável pela correspondência
Email: Mikushina@ios.uran.ru
Rússia, 22/20 ul. S. Kovalevskoy, Ekaterinburg, 620041
A. Shishmakov
I. Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences
Email: Mikushina@ios.uran.ru
Rússia, 22/20 ul. S. Kovalevskoy, Ekaterinburg, 620041
L. Petro
I. Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences
Email: Mikushina@ios.uran.ru
Rússia, 22/20 ul. S. Kovalevskoy, Ekaterinburg, 620041
