Oxidation of 2,3,6-trimethylphenol to 2,3,5-trimethyl-1,4-benzoquinon over binary xerogels TiO2—SiO2 in the three-phase system
- 作者: Mikushina Y.V.1, Shishmakov A.B.1, Petro L.A.1
- 
							隶属关系: 
							- I. Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences
 
- 期: 卷 66, 编号 4 (2017)
- 页面: 677-682
- 栏目: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/240416
- DOI: https://doi.org/10.1007/s11172-017-1791-y
- ID: 240416
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详细
The technique of synthesis of 2,3,5-trimethyl-1,4-benzoquinon via catalytic oxidation of 2,3,6-trimethylphenol in H2O2—H2O—PhCH3 system with vibrational stirring is developed. Xerogels TiO2 and TiO2—SiO2 were used as catalysts in the process. The effect of physicochemical properties of xerogels on the course and characteristics of oxidation is studied.
作者简介
Yu. Mikushina
I. Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences
							编辑信件的主要联系方式.
							Email: Mikushina@ios.uran.ru
				                					                																			                												                	俄罗斯联邦, 							22/20 ul. S. Kovalevskoy, Ekaterinburg, 620041						
A. Shishmakov
I. Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences
														Email: Mikushina@ios.uran.ru
				                					                																			                												                	俄罗斯联邦, 							22/20 ul. S. Kovalevskoy, Ekaterinburg, 620041						
L. Petro
I. Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences
														Email: Mikushina@ios.uran.ru
				                					                																			                												                	俄罗斯联邦, 							22/20 ul. S. Kovalevskoy, Ekaterinburg, 620041						
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